Prediction of Aquifer Vulnerability to Pesticides Using Fuzzy Rule-Based Models at the Regional Scale     

《自然地理学》2013,34(2):130-153

Contamination of ground water has been a major environmental concern in recent years. The potential for ground-water contamination by pesticides depends on porous media, solute, and hydrologic parameters. Although sophisticated deterministic computer models are available for assessing aquifer-contamination potential on a site-by-site basis, most deterministic models are too complex for vulnerability assessment on a regional scale because they require input data that are spatially and temporally variable, and which may not be available at this scale. Therefore, development of an affordable model that is robust under conditions of uncertainty at the watershed scale with minimum input of field data becomes a useful ground-water management tool. The purpose of this study was to examine the usefulness of fuzzy rule-based techniques in predicting aquifer vulnerability to pesticides at the regional scale. The objectives were to (1) develop fuzzy rule-based models using the same input parameters contained in an index-based model (i.e., the modified DRASTIC model), (2) determine the sensitivity of fuzzy rule model predictions, (3) compare the outputs of the fuzzy rule-based models with those of the modified DRASTIC model and with the results of aquifer water-quality analyses, and (4) examine the spatial variability of field parameters around contaminated wells of the Alluvial aquifer in Woodruff County Arkansas. The fuzzy rule-based model for objective (1) was developed using similar parameter weights and ratings as the modified DRASTIC model. For objective (2), fuzzy rule-based models were created using fewer parameters than the modified DRASTIC model. Sensitivity of the fuzzy rule-based models was determined using different combinations of weights of the four input parameters in DRASTIC. It was found that variations in the weights of the input parameters and number of fuzzy sets influenced the location of the aquifer-vulnerability categories as well as the area within each fuzzy category. The fuzzy rule models tended to predict somewhat higher vulnerabilities of the Alluvial aquifer than the modified DRASTIC model. The fuzzy rule base that had the soil-leaching index (S) as the highest weight was chosen as the best fuzzy rule model in predicting potential contamination by pesticides of the aquifer. In general, the fuzzy rule models tended to overestimate the vulnerability of the aquifer in the study area.  相似文献   

Ardières-Morcille in the Beaujolais,France: A research catchment dedicated to study of the transport and impacts of diffuse agricultural pollution in rivers     

Véronique Gouy  Lucie Liger  Samira Ahrouch  Chloé Bonnineau  Nadia Carluer  Arnaud Chaumot  Marina Coquery  Aymeric Dabrin  Christelle Margoum  Stéphane Pesce 《水文研究》2021,35(10):e14384

The 8-km² Morcille catchment, which is a sub-catchment of the 150-km² Ardières catchment in the Beaujolais region of France, is one of the first sites in Europe where research has been conducted on surface water contamination by pesticides. A consolidated hydrological and chemical dataset has been set up with data collected since 2002 on the Morcille River and since 2011 on the Ardières River. Additional data on the ecotoxicological and ecological impacts of pesticides on aquatic microbial communities and macroinvertebrates has also been recorded in both rivers since 2005. The ‘Site Atelier Ardières-Morcille Dataset’ described here combines rainfall and stream water height measurements at gauged stations with concentrations of two trace elements and nine pesticides (mainly herbicides, fungicides and some of their metabolites) in both the Ardières and Morcille rivers. All contaminant concentration data showed spatial and temporal variability in water quality associated with pesticide use and rainfall patterns. This long-term monitoring framework made it possible to estimate the persistence of two herbicides (diuron and norflurazon) after legislation banning them. It took 4 years for diuron and more than 10 years for norflurazon concentrations to fall below 0.1 μg/L. Concurrent biological data showed a gradient of impacts consistent with chemical anthropogenic pressure, and rapid recovery of phototrophic microbial communities after the diuron ban. Finally, monitoring data on pesticide transport in a grassed strip set on a slope of the Morcille catchment confirmed that vegetative filter strips can effectively reduce diuron fluxes in surface runoff (>80% abatement) and infiltration water (>70% abatement). The full dataset offers a valuable resource for the validation of hydrological models and the development of global approaches to better understand the pressure–transport–exposure–impact chain and aquatic community resilience at the small catchment scale.  相似文献   

Polychlorinated biphenyls and organochlorine pesticides in plastics ingested by seabirds     

Fernanda Imperatrice Colabuono  Satie Taniguchi  Rosalinda Carmela Montone 《Marine pollution bulletin》2010,60(4):630-634

The occurrence of plastic objects in the digestive tract was assessed in eight species of Procellariiformes collected in southern Brazil and the occurrence of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in the ingested plastics pellets and plastic fragments was evaluated. PCBs were detected in plastic pellets (491 ng g⁻¹) and plastic fragments (243-418 ng g⁻¹). Among the OCPs, p,p′-DDE had the highest concentrations, ranging from 68.0 to 99.0 ng g⁻¹. The occurrence of organic pollutants in post-consumer plastics supports the fact that plastics are an important source carrying persistent organic pollutants in the marine environment. Although transfer through the food chain may be the main source of exposure to POPs to seabirds, plastics could be an additional source for the organisms which ingest them, like Procellariiformes which are the seabirds most affected by plastic pollution.  相似文献   

Stable isotopes of carbon and nitrogen in the study of organochlorine contaminants in albatrosses and petrels     

Fernanda I. Colabuono  Viviane Barquete  Satie Taniguchi  Peter G. Ryan  Rosalinda C. Montone 《Marine pollution bulletin》2014

Carbon and nitrogen stable isotopes in albatrosses and petrels collected off southern Brazil were compared with concentrations of organochlorine contaminants (OCs). δ¹³C and δ¹⁵N values, as well as OCs concentrations, exhibited a high degree of variability among individuals and overlap among species. δ¹³C values reflected latitudinal differences among species, with lower values found in Wandering and Tristan Albatrosses and higher values found in Black-browed and Atlantic Yellow-nosed Albatrosses and White-chinned Petrels. Some relationships were found between OCs and stable isotopes, but in general a partial ‘uncoupling’ was observed between OCs concentrations and stable isotopes ratios (especially for δ¹⁵N). δ¹³C and δ¹⁵N values in Procellariiformes tissues during the non-breeding season appear to be a better indicator of foraging habitats than of trophic relationships, which may partially explain the high degree of variability between concentrations of OCs and stable isotopes ratios in birds with a diversified diet and wide foraging range.  相似文献   

Historical records of organic pollutants in sediment cores     

《Marine pollution bulletin》2014,78(1-2):26-42

Analyses of sediment core samples are primary sources of historical pollution trends in aquatic systems. Determining organic compounds, such as POPs, in the dated sediments enables the estimation of their temporal concentration changes and the identification of the contaminant origin in local regions. Wars, large-scale fires, economical transitions, and bans on certain chemicals are reflected in the sediment organic compound concentrations. The high POP concentrations in surficial sediments suggest that these chemicals, even after being banned, remain in the environment. Furthermore, vertical profiles can help in understanding the sedimentation process and in estimating effective countermeasures against pollution. Moreover, studies published during the period 1991–2013 on PAHs, PCBs, OCPs, dioxins and dioxin-like compound concentrations in sediment core samples are reviewed.  相似文献   

Assessment of pesticide contamination of groundwater in New Zealand     

Murray E. Close 《新西兰海洋与淡水研究杂志》2013,47(2):257-266

Groundwater contamination by pesticides may be affected by the amounts of pesticide used, the mobility and degradation characteristics of the pesticides, and the vulnerability of an area to pollution. An index of potential pollution was developed based on these factors, with the groundwater vulnerability being measured using the DRASTIC ranking method. Seventeen regions were selected from throughout New Zealand where significant pesticides have been applied and there is an underlying groundwater system. They were ranked according to this index of potential pollution. The sensitivity of the ranking to various formulations and weightings of the index was examined. Three regions (Poverty Bay, Te Puke, and Motueka) were generally highly ranked for a wide range of index formulations. Six of the higher‐ranked regions were selected for sampling in the second phase of the study.  相似文献   

Composition and distribution of organochlorine pesticide residues in surface sediments from the Wu-Shi River Estuary,Taiwan   总被引：23，自引：0，他引：23  

Doong RA  Peng CK  Sun YC  Liao PL 《Marine pollution bulletin》2002,45(1-12):246-253

The contamination of organochlorine pesticides (OCPs) in sediments from the Wu-Shi River estuary was investigated to evaluate the pollution potentials and distribution of OCPs in central Taiwan. A total of 19 sediment samples were collected at five sampling stations along the River estuary. The concentrations of OCPs were in the range of 0.99–14.5 ng/g-dry weight (dw) for ΣHCH (-, β-, γ-, δ-HCH), 0.46–13.4 ng/g-dw for Σcyclodiene and 0.53–11.4 ng/g-dw for ΣDDT (p,p^′-DDD, p,p^′-DDE, p,p^′-DDT). The mean concentrations of ΣHCH, Σcyclodiene and ΣDDT were 3.79, 4.87 and 2.51 ng/g-dw, respectively. The total concentrations of OCPs correspond to 1.73–71.9 μg/g-OC when normalized to TOC contents. Among the organochlorine pesticides, endosulfan sulfate, β-HCH, and p,p^′-DDD were the most dominant compounds in the sediments with the average concentrations of 1.97, 3.43 and 2.08 ng/g, respectively. Also, different contamination patterns among sampling seasons were observed. The measured concentrations of OCPs collected in spring were higher than those in autumn and winter. A linear relationship between sediment characteristics and OCP residues was also demonstrated. The results obtained in this study show that there still exist a variety of organochlorine pesticide residues in the sediments from the near shore of central Taiwan.  相似文献   

Residue levels of HCHs,DDTs and PCBs in shellfish from coastal areas of east Xiamen Island and Minjiang Estuary,China   总被引：8，自引：0，他引：8  

Chen W  Zhang L  Xu L  Wang X  Hong L  Hong H 《Marine pollution bulletin》2002,45(1-12):385-390

Shellfish samples were collected from the coastal cultivating areas of east Xiamen Island and Minjing Estuary, China and analyzed for hexachlorocyclohexanes (HCHs), DDTs and polychlorinated biphenyls (PCBs) by GC. Concentration ranges of HCHs, DDTs and PCBs in the coastal area of east Xiamen Island were 0.18–345, 75.2–2143 and ND-23 ng g⁻¹ dry wt., respectively; those for Minjiang Estuary were ND-5.07, 21.5–2396 and ND-6.78 ng g⁻¹ dry wt., respectively. The results showed that the organochlorines were evidently accumulated in marine bivalve molluscs, particularly in oyster. The concentrations of organocholorine pollutants in shellfish samples varied with the sampling locations, the season of collection and organism species, but were generally higher than those in the sediments. The concentrations of DDTs in the shellfish were high as compared with HCHs and PCBs, so that DDTs can be considered as the typical organochlorines in the survey areas. The residue levels and compositions of HCHs, DDTs and PCBs are discussed.  相似文献   

Geographical distribution and accumulation features of organochlorine residues in bivalves from coastal areas of South Korea   总被引：26，自引：0，他引：26  

Kim SK  Oh JR  Shim WJ  Lee DH  Yim UH  Hong SH  Shin YB  Lee DS 《Marine pollution bulletin》2002,45(1-12):268-279

As a part of Mussel Watch Program in Korea, the contamination levels and accumulation features of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were assessed for 82 bivalve samples collected from 66 sites along the entire coast of Korea. The dry weight based ∑PCBs and ∑OCPs ranged from 4.4 ng g⁻¹ to 422.0 ng g⁻¹ (geometric MEAN=36.9 ng g⁻¹) and from 9.95 ng g⁻¹ to 131.37 (34.88) ng g⁻¹, respectively. PCB was predominant in Korean coast, followed by DDTs, HCHs, and Chlordanes. From the observed log normal distribution of PCB and each OCP, low- and high-levels were defined as geometric mean ±1 S.D., respectively. The levels at the sites near urban and/or industrial areas often exceeded the high-levels and the spatial distributions of ∑DDTs and ∑CHLs were correlated with that of ∑PCBs, indicating terrestrial input pathways. Even distribution of ∑HCHs suggested a possibility of atmospheric input pathway of HCHs. The observed isomer ratios of DDTs, HCHs, and CHLs indicated that aging has occurred.  相似文献   

西藏错鄂湖和羊卓雍湖水体及沉积物中有机氯农药的初步研究   总被引：32，自引：0，他引：32  

张伟玲  张干  祁士华  彭平安 《地球化学》2003,32(4):363-367

对2002年5月采集的西藏错鄂湖和羊卓雍湖的水和沉积物样品进行了实验及分析。结果表明，这2个高原湖泊均不同程度地受到有机氯农药的污染，并具有多种有机氯农药的同时存在、在沉积柱上近表层没有含量下降趋势以及南部的羊卓雍湖污染程度高于藏北的错鄂湖等特点，反映出湖泊中的有机氯农药有可能是随孟加拉湾洋暖流由南向北带人的。两个湖泊的水与沉积物中滴滴涕(DDTs)和六六六(HCHs)含量甚至与我国东部地区的一些淡水水体相近，这种现象很可能表明，大气沉降的有机氯农药可在青藏高原湖泊水体与沉积物中发生一定程度的累积。长远地看，这一过程将可能对青藏高原野生动物产生负面影响。  相似文献